螺旋烯
钙钛矿(结构)
聚合物
材料科学
纳米技术
化学物理
化学工程
光电子学
化学
复合材料
有机化学
工程类
分子
作者
Yuyan Zhang,Lifei He,Yaohang Cai,Jing Zhang,Peng Wang
标识
DOI:10.1002/anie.202401605
摘要
The strategic design of solution‐processable semiconducting polymers possessing both matched energy levels and elevated glass transition temperatures is of urgent importance in the progression of thermally robust n‐i‐p perovskite solar cells with efficiencies exceeding 25%. In this work, we employed direct arylation polymerization to achieve the high‐yield synthesis of three aza[5]helicene‐derived copolymers with distinct HOMO energy levels and exceptional glass transition temperatures. Upon integration of these semiconducting polymers into formamidinium lead triiodide‐based perovskite solar cells, marked disparities in photovoltaic parameters manifest, primarily stemming from variations in the electrical conductivity and film morphology of the hole transport layers. The p‐A5HP‐E‐POZOD‐E copolymer, featuring a conjugated main chain comprising alternating repeats of aza[5]helicene, ethylenedioxythiophene, phenoxazine, and ethylenedioxythiophene, attains an initial average efficiency of 25.5%, markedly surpassing reference materials such as spiro‐OMeTAD (23.0%), PTAA (17.0%), and P3HT (11.6%). Notably, p‐A5HP‐E‐POZOD‐E exhibits a high cohesive energy density, resulting in enhanced Young's modulus and diminished external species diffusion coefficients, thereby conferring perovskite solar cells with exceptional 85°C tolerance and operational stability.
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