胺化
试剂
催化作用
组合化学
胺气处理
化学
功能群
有机化学
聚合物
作者
Jian-Guo Qin,Shixuan Jiang,Xiaofeng Luo,Tianqiang Wang,Peihua Liu,Bingxiang Yuan,Rulong Yan
摘要
The synthesis of 3-aminopyrrole using the amination reagent nitrosoarenes and homopropargylic amines catalyzed by I2 through cyclization and amination has been developed. This protocol features excellent functional group tolerance and mild reaction conditions, yielding 3-aminopyrroles in moderate to good yields without a metal catalyst. This method realizes the construction and amination of the 3-aminopyrroles in which nitrosoarenes serve as the amine source and oxidant.
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