电化学
材料科学
阴极
锂(药物)
钠
化学工程
透射电子显微镜
离子
电极
分析化学(期刊)
纳米技术
化学
冶金
色谱法
物理化学
工程类
内分泌学
有机化学
医学
作者
L. Wang,Hualing Tian,Yang Xiang,Yanfei Cai,Ziwei Gao,Zhi Su
出处
期刊:Micromachines
[Multidisciplinary Digital Publishing Institute]
日期:2023-12-21
卷期号:15 (1): 15-15
摘要
With their advantages of abundant raw material reserves, safety, and low toxicity and cost, sodium-ion batteries (SIBs) have gained increasing attention in recent years. Thanks to a high theoretical specific capacity (124 mAh g−1), a high operating voltage (about 3.2 V), and a very stable three-dimensional layered structure, sodium ferric fluorophosphate (Na2FePO4F, NFPF) has emerged as a strong candidate to be used as a cathode material for SIBs. However, applications are currently limited due to the low electronic conductivity and slow ion diffusion rate of NFPF, which result in a low actual specific capacity and a high rate performance. In this study, the authors used a high-temperature solid-phase technique to produce Na2−xLixFePO4F/C (0 ≤ x ≤ 2) and evaluated the impact on electrode performance of materials with different Na+ and Li+ contents (values of x). Transmission electron microscopy (TEM) and X-ray diffraction (XRD) were also used to analyze the material’s crystal structure and nanostructure. The results show that the material had the best room-temperature performance when x = 0.5. At a charge–discharge rate of 0.1 C, the first discharge-specific capacity of the resulting Na1.5Li0.5FePO4F/C cathode material was 122.9 mAh g−1 (the theoretical capacity was 124 mAh g−1), and after 100 cycles, it remained at 118 mAh g−1, representing a capacity retention rate of 96.2% and a Coulomb efficiency of 98%. The findings of this study demonstrate that combining lithium and sodium ions improves the electrochemical performance of electrode materials.
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