Hydrophilic 1T‐WS2 Nanosheet Arrays toward Conductive Textiles for High‐Efficient and Continuous Hydroelectric Generation and Storage

Abstract Flexible hydroelectric generators (HEGs) are promising self‐powered devices that spontaneously derive electrical power from moisture. However, achieving the desired compatibility between a continuous operating voltage and superior current density remains a significant challenge. Herein, a textile‐based van der Waals heterostructure is rationally designed between conductive 1T phase tungsten disulfide@carbonized silk (1T‐WS 2 @CSilk) and carbon black@cotton (CB@Cotton) fabrics with an asymmetric distribution of oxygen‐containing functional groups, which enhances the proton concentration gradients toward high‐performance wearable HEGs. The vertically staggered 1T‐WS 2 nanosheet arrays on the CSilk fabric provide abundant hydrophilic nanochannels for rapid carrier transport. Furthermore, the moisture‐induced primary battery formed between the active aluminum (Al) electrode and the conductive textiles introduces the desired electric field to facilitate charge separation and compensate for the decreased streaming potential. These devices exhibit a power density of 21.6 µW cm −2 , an open‐circuit voltage ( V oc ) of 0.65 V sustained for over 10 000 s, and a current density of 0.17 mA cm −2 . This performance makes them capable of supplying power to commercial electronics and human respiratory monitoring. This study presents a promising strategy for the refined design of wearable electronics.