表面改性
烯丙基重排
氧化磷酸化
群(周期表)
化学
催化作用
金属
组合化学
有机化学
生物化学
物理化学
作者
Amaan M. Kazerouni,Quincy A. McKoy,Simon B. Blakey
摘要
catalysts for allylic functionalization. Since these initial reports, a number of key intermolecular Co-, Rh-, and Ir-catalyzed allylic C-H functionalization reactions have been reported, offering significant complementarity to the Pd-catalyzed reactions. Herein, we report a summary of recent advances in intermolecular allylic C-H functionalization via group IX-metal π-allyl complexes. Mechanism-driven development of new catalysts is highlighted, and the potential for future developments is discussed.
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