MXene-Coated Air-Permeable Pressure-Sensing Fabric for Smart Wear

Considering the fast development of wearable electronics and soft robotics, pressure sensors with high sensitivity, durability, and washability are of great importance. However, the surface modification of fabrics with high-sensitivity active materials requires that issues associated with poor interface adhesion and stability are resolved. In this study, we explored the key factors for firmly bonding MXene to fabric substrates to fabricate wearable and washable pressure sensing fabric. The interactions between MXene and various fabrics were elucidated by investigating the adsorption and binding capacities. The natural rough surface of cotton fibers also promoted the firm adsorption of MXene. As a result, MXene was difficult to detach, even with mechanical washing and ultrasonic treatment. Further, the abundant functional groups on the MXene surface were conducive to interfacial interactions with cotton fibers. An increase in the amount of fluorine-containing functional groups also improved the hydrophobicity of the fabric surface. The good force-sensitive resistance of MXene-coated cotton allowed this pressure-sensing fabric to function as a flexible pressure sensor, which showed a high gauge factor (7.67 kPa–1), a rapid response and relaxation speed (<35 ms), excellent stability (>2000 cycles), and good washing durability. Further, the as-fabricated flexible pressure sensor was demonstrated as a wearable human–machine interface that supported multitouch interactions and exhibited a rapid response. Thus, this work provides a new approach for developing next-generation high-sensitivity wearable pressure sensors.