过硫酸盐
苯酚
化学
催化作用
核化学
吸附
动力学
降级(电信)
化学工程
活性炭
水溶液
腐植酸
光化学
无机化学
有机化学
工程类
物理
电信
量子力学
计算机科学
作者
Pu-Can Guo,Hai-Bin Qiu,Chuan-Wang Yang,Xin Zhang,Xin-Yue Shao,Yang-Li Lai,Guo-Ping Sheng
标识
DOI:10.1016/j.jhazmat.2020.123846
摘要
• A MnO x @OMC composite was prepared for persulfate activation with high efficiency. • Phenol was effectively removed and detoxified by persulfate activation. • Synergistic effect between MnOx and OMC enhanced phenol removal performance. • A new kinetic model for phenol decay by persulfate was proposed. Persulfate-based advanced oxidation technology exhibits great potential for hazardous organic pollutant removal from wastewater. Acceleration of pollutant degradation needs to be elucidated, particularly for heterogeneous catalytic systems. In this study, manganese oxide ordered mesoporous carbon composites (MnO x @OMC) were prepared by nano-casting method and used for persulfate activation to degrade phenol. Kinetics analysis indicate that the rate of phenol degradation using MnO x @OMC composites was improved by 34.9 folds relative to that using a mixture of MnO x and OMC. The phenol toxicity towards Caenorhabditis elegans could be totally reduced within 8 min. The different roles of MnO x and OMC in persulfate activation were confirmed to validate their synergistic effect. MnO x provided major active sites for persulfate activation in accordance with the surface Mn 3+ /Mn 4+ cycle to induce SO 4 •− radicals. The OMC matrix provided the adsorption sites to enrich phenol molecules on the catalytic surface and promote the interfacial electron transfer process for persulfate activation. Moreover, a novel kinetic model with two distinct kinetic stages was established to verify the effects of phenol and persulfate on phenol removal.
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