插层(化学)
氧化钒
阴极
水溶液
材料科学
钒
储能
无机化学
离子
电解质
电化学
氧化物
化学工程
化学
冶金
电极
物理化学
热力学
有机化学
功率(物理)
工程类
物理
作者
Pinji Wang,Xiaodong Shi,Zhuoxi Wu,Shan Guo,Jiang Zhou,Shuquan Liang
出处
期刊:Carbon energy
[Wiley]
日期:2020-03-19
卷期号:2 (2): 294-301
被引量:83
摘要
Abstract Aqueous Zn‐ion batteries (ZIBs) hold great potential in large‐scale energy storage systems due to the merits of low‐cost and high safety. However, the unstable structure of cathode materials and sluggish (de)intercalation kinetics of Zn 2+ pose challenges for further development. Herein, highly reversible aqueous ZIBs are constructed with layered hydrated vanadium oxide as a cathode material. The electrochemical performances are further tested with the optimized electrolyte of 3M Zn(CF 3 SO 3 ) 2 and a cut‐off voltage of 0.4 to 1.3 V, exhibiting a remarkable capacity of 290 mAh g −1 at 0.5 A g −1 , and long‐term cycling stability at high current density. Furthermore, the Zn 2+ storage mechanism of V 3 O 7 ⋅H 2 O is recognized as a highly reversible (de)intercalation process with good structural stability, implying the potential application in the field of large‐scale energy storage.
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