侧链
膜
离子交换
阳离子聚合
氢氧化物
碱性燃料电池
化学
电导率
高分子化学
连接器
化学工程
材料科学
有机化学
离子
聚合物
物理化学
工程类
操作系统
生物化学
计算机科学
作者
Xiaomeng Chu,Jiaye Liu,Shasha Miao,Lei Liu,Yingda Huang,Erjun Tang,Shaojie Li,Xuteng Xing,Nanwen Li
标识
DOI:10.1016/j.memsci.2021.119172
摘要
Side-chain functionality is critical to achieve highly conductive and chemically stable anion exchange membrane (AEM) materials. Herein, two series of quaternized poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) having different lengths (n or m) of cationic side-chains were designed and prepared, including PPO-C-nQA with a triazole-containing linker and PPO-mQA without triazole groups in the side chains. The effect of the side-chain functionality on the properties of AEMs has been systematically investigated. Long cationic side chains in PPO-mQA membranes induced the formation of obvious microphase-separated morphology. However, PPO-C-nQA membranes with a triazole-containing linker showed a considerable higher hydroxide conductivity than that of PPO-mQA membranes, due to the developed hydrogen-bond networks between triazole and water/hydroxide. High retention of conductivity and low degree of crosslinking were observed for the AEMs with longer side-chains (PPO-C-3QA, PPO-C-4QA, PPO-6QA, and PPO-7QA) in the alkaline stability testing under 10 M NaOH at 80 °C for 250 h, indicating their excellent stability. Moreover, a single H2/O2 AEMFC with these side-chain type AEMs demonstrated that PPO-C-1QA with highest conductivity exhibited a peak power density of 141.3 mW cm−2 at a current density of 320 mA cm−2.
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