化学
块(置换群论)
烯烃纤维
组合化学
背景(考古学)
小分子
简单(哲学)
概括性
联轴节(管道)
有机化学
生物化学
哲学
心理治疗师
聚合物
古生物学
几何学
工程类
认识论
生物
机械工程
数学
心理学
作者
Eric M. Woerly,Jonathan E. Miller,Martin D. Burke
出处
期刊:Tetrahedron
[Elsevier]
日期:2013-09-01
卷期号:69 (36): 7732-7740
被引量:34
标识
DOI:10.1016/j.tet.2013.05.050
摘要
Iterative cross-coupling represents a potentially general approach for the simple, efficient, and flexible construction of a wide range of functional small molecules. In this context, (1-bromovinyl)-N-methyliminodiacetic acid (MIDA) boronate is a very useful building block for small molecule synthesis. This compound can serve as a starting material for the preparation of a wide range of 1,1-disubstituted olefin-containing MIDA boronates. This compound can also be used for the iterative cross-coupling-based synthesis of various 1,1-disubstituted olefin-containing targets. Collectively, these results contribute to the expanding generality of the MIDA boronate platform.
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