材料科学
电催化剂
过电位
无定形固体
丝带
化学工程
吉布斯自由能
合金
密度泛函理论
非晶态金属
化学物理
电化学
冶金
物理化学
复合材料
结晶学
计算化学
热力学
电极
化学
工程类
物理
作者
Hongyan Wang,Ran Wei,Xiumin Li,Xuli Ma,Xiaogang Hao,Guoqing Guan
标识
DOI:10.1016/j.jmst.2020.06.045
摘要
Proximal configuration of dissimilar metal atoms in amorphous high-entropy-alloys (HEAs) always result in interatomic d-band ligand effect, dense defect distribution, coordinatively unsaturated sites, high potential energy, and loose atom bonding. Herein, nanostructured amorphous Fe29Co27Ni23Si9B12 HEA ribbon is fabricated via a melt spinning method combined with electrochemical corrosion etching process, which is applied as the potential oxygen evolution reaction electrocatalyst. It is found that there are micro/nano pits on the surface of etched amorphous Fe29Co27Ni23Si9B12 ribbons. Various elements of HEAs bond with each other to form a highly disordered configuration, which could result in an optimized bonding energy and enhanced intrinsic catalytic activity. The electrocatalysis activity measurements indicate that the amorphous HEA endows a much higher activity than the crystalline one, which is further improved by the electrochemical etching treatment. Especially, the HEA ribbon etched for 3 h requires a low overpotential of 230 mV to afford 10 mA cm-2 current density. In addition, density functional theory calculations demonstrate that the amorphous structure can weaken the interaction between the surface of Fe29Co27Ni23Si9B12 alloy and the intermediates, leading to an optimized adsorption Gibbs free energy.
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