化学
生物催化
猝灭(荧光)
绿色化学
镁
试剂
酒
有机化学
反应机理
偶联反应
离子液体
催化作用
量子力学
荧光
物理
作者
Jack M. Harrowfield,R. C. Hart,Claire R. Whitaker
摘要
Mechanically induced reactions of magnesium with halonaphthalenes, under solvent-free conditions, provide the corresponding Grignard reagents in good yields. The use of excess Mg to obtain a solid (powder) product, however, means that quenching reactions using aromatic ketones involve some contribution from McMurry coupling of these species, in addition to alcohol formation by the true quenching process.
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