光催化
表面改性
化学
生物结合
催化作用
组合化学
纳米技术
光催化
有机化学
物理化学
材料科学
作者
Natalie Holmberg‐Douglas,David A. Nicewicz
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2021-09-29
卷期号:122 (2): 1925-2016
被引量:355
标识
DOI:10.1021/acs.chemrev.1c00311
摘要
The fields of C-H functionalization and photoredox catalysis have garnered enormous interest and utility in the past several decades. Many different scientific disciplines have relied on C-H functionalization and photoredox strategies including natural product synthesis, drug discovery, radiolabeling, bioconjugation, materials, and fine chemical synthesis. In this Review, we highlight the use of photoredox catalysis in C-H functionalization reactions. We separate the review into inorganic/organometallic photoredox catalysts and organic-based photoredox catalytic systems. Further subdivision by reaction class─either sp2 or sp3 C-H functionalization─lends perspective and tactical strategies for use of these methods in synthetic applications.
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