材料科学
化学工程
碳化
法拉第效率
生物相容性
碳纤维
多硫化物
吸附
超级电容器
生物量(生态学)
环境友好型
多孔性
电解质
纳米技术
电化学
电极
化学
复合材料
有机化学
冶金
生态学
复合数
生物
物理化学
扫描电子显微镜
工程类
地质学
海洋学
作者
Jiaqing Cui,Jia Liu,Xing Chen,Jiashen Meng,Shanyue Wei,Tao Wu,Yan Wang,Yiming Xie,Can‐Zhong Lu,Xingcai Zhang
出处
期刊:Carbon
[Elsevier BV]
日期:2022-04-23
卷期号:196: 70-77
被引量:22
标识
DOI:10.1016/j.carbon.2022.04.034
摘要
The conversion of biomass waste into functional carbon materials is an environmentally friendly solution with diverse applications for a sustainable world. Here, we report an approach to fabricate the Ganoderma Lucidum waste-derived erythrocyte-like N, O self-doped porous biomass carbon (GL800) with a high graphitization degree by a facile carbonization and activation method. The prepared GL800 showed a relatively high specific surface area (2407.5 m2 g−1) and a porous structure like the red blood cell, which affords enough space to accommodate active sites and are easy for electrolytes to infiltrate. Due to the synergistic effect of the rich N, O self-doped elements and porous structures, GL800 shows strong chemical adsorption and physical confinement for polysulfide. Lithium-sulfur batteries using GL800 electrodes exhibited a high discharge capacity of 1367.8 mA g−1 at 0.1C and desirable rate performance. Furthermore, the battery has a capacity retention rate after 300 cycles at 0.5C with high coulombic efficiency (99%). Together with the good biocompatibility and biodegradability of the prepared material, it has a high potential for diverse applications in energy storage, environmental remediation, wearable electronics, biomedicine, and other areas, providing a Nature-derived solution with good sustainability.
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