催化作用
光催化
介电谱
化学工程
浸出(土壤学)
电子转移
化学
兴奋剂
电子顺磁共振
扫描电子显微镜
光电流
降级(电信)
石墨氮化碳
材料科学
比表面积
电化学
核化学
光化学
电极
有机化学
复合材料
工程类
物理化学
物理
土壤科学
土壤水分
电信
光电子学
核磁共振
计算机科学
环境科学
作者
Yu Zhang,Xing Chen,Minshu Cui,Zhi Guo,Yihan Chen,Kangping Cui,Zhao-Gang Ding,Rohan Weerasooriya
标识
DOI:10.1016/j.jece.2022.107406
摘要
We fabricated iron-doped carbon nitride on a diatomite surface through a single-step polymerization (FGD-x, where x represents Fe loading content). The FGD-x efficiently degrades tetracycline hydrochloride by a collaborative photo-Fenton process. The FGD-3 (FeCl3 loading 75 mg) showed the best catalytic performance in TC degradation with minimal H2O2 (viz. 1 mmol/L) at a wide pH range (2.0–7.0). Under optimized conditions, the FGD-3 can degrade 98.3% of 20.0 mg/L TC at pH 4.0 within 100 min under visible light irradiation. The scanning electron microscopic and X-ray photon spectroscopic data show that iron is successfully doped on g-C3N4. Electrochemical impedance spectroscopy and transient photocurrent performance analyses confirmed that photogenerated electrons rapidly transfer at FGD-3 and solution interface. Free radical quenching experiments and electron spin resonance analysis show that h+, ∙O2-, and ∙OH can degrade TC efficiently. Besides, FGD-3 has an ultra-high catalytic activity and extremely low iron leaching after repeated use. The FGD-3 provides a feasible way to design a new photo-Fenton catalyst for the destruction of organic pollutants from water.
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