纳滤
膜
聚酰胺
化学工程
材料科学
界面聚合
薄膜复合膜
单体
纳米复合材料
共价有机骨架
高分子化学
图层(电子)
渗透
聚合物
反渗透
纳米技术
复合材料
化学
渗透
工程类
生物化学
多孔性
作者
Linhan Ni,Ke Chen,Jia Xie,Qin Li,Junwen Qi,Chaohai Wang,Xiuyun Sun,Jiansheng Li
标识
DOI:10.1016/j.memsci.2022.120253
摘要
The performance of polyamide-based thin film nanocomposite (TFN) membranes essentially hinges on nanofillers, polyamide (PA) selective layer and the interaction between them. Incorporating synthesized nanofillers into PA layer has attracted significant attention, yet this fabrication route suffers from the unsatisfactory interfacial compatibility between nanofillers and polymer matrix. As pure organic nanofillers, covalent organic frameworks (COFs), however, are constrained by their large pore size and demanding synthesis condition. Herein, COF TpHz was synchronously synthesized with the interfacial polymerization (IP) process of PA layer to fabricate COFs incorporated TFN membranes. The addition of TpHz was optimized by controlling the content of monomers and the resultant TFN membrane achieved enhanced nanofiltration performance thanks to the in-situ synthesized TpHz. At ambient temperature, the prepared membrane showed higher permeance (23.6 L m2 h−1 bar−1) and salt rejection (96.9%) than the pristine thin film composite (TFC) membrane under 4 bar toward 1 g/L Na2SO4 solution, corresponding to an improvement of 44.8% and 3.2% of permeance and rejection, respectively. Meanwhile, the anti-fouling property of the prepared membrane was also improved compared with TFC membrane. This in-situ interfacial polymerization (IIP) strategy proposes a new idea for the preparation of COFs incorporated TFN membranes, revealing its promising prospect in desalination.
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