MXenes公司
超级电容器
电极
材料科学
电容
纳米技术
蚀刻(微加工)
电化学
纳米颗粒
储能
化学工程
电容器
电解质
假电容
光电子学
功率密度
图层(电子)
化学
工程类
物理化学
作者
Xuefeng Zhang,Yong Liu,Shuangshi Dong,Jinlong Yang,Xudong Li
标识
DOI:10.1016/j.jallcom.2019.03.219
摘要
MXenes is one of the most promising flexible electrode materials for supercapacitor. However, the nanosheets in the MXenes electrode by vacuum filtration are prone to restack during preparation, which largely hinders the full utilization of their surfaces and active sites. In this contribution, the self-restacking of MXene nanosheets (prepared by etching with HCl + LiF) could be prevented effectively by introducing MXene nanoparticles (prepared by etching with HF) as interlayer spacers. The Ti3C2Tx-10 flexible (the electrode with 10% mass fraction nanoparticles) exhibits an excellent specific capacitance of 372 F g−1 at 1 A g−1 which is much higher than that of Ti3C2Tx film, and an impressive cycling stability up to 95% capacitance retention after 5000 cycles. The significant improvement in electrochemical performance is mainly due to that the open sandwich-like structure of the flexible electrode based on multi-scaled Ti3C2Tx provides huge surface area and more active sites.
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