化学
催化作用
氧化磷酸化
键裂
铜
氧化裂解
劈理(地质)
药物化学
有机化学
生物化学
岩土工程
断裂(地质)
工程类
作者
Chun Zhang,Xiaoyang Wang,Ning Jiao
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2014-05-08
卷期号:25 (10): 1458-1460
被引量:19
标识
DOI:10.1055/s-0033-1341243
摘要
An aerobic oxidative C–C bond cleavage of 1,3-diaryldiketones for the synthesis of 1,2-diketones by using O2 as the oxidant has been developed. Control experiments illustrate that the copper catalyst not only assist the aerobic oxidative process of 1,3-diketones, but also catalyze the 1,2-Wagner–Meerwein-type rearrangement process.
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