氨氧化
苯甲腈
催化作用
化学
苯甲醇
腈
选择性
酰胺
酒精氧化
有机化学
丙烯腈
无机化学
共聚物
聚合物
作者
Tamao Ishida,Hiroto Watanabe,Takashi Takei,Azumi Hamasaki,Makoto Tokunaga,Masatake Haruta
标识
DOI:10.1016/j.apcata.2012.03.006
摘要
Transition metal oxides (MnO2, Co3O4, and NiO) are catalytically active for the ammoxidation of alcohols to nitriles. In particular, MnO2 exhibited remarkably high catalytic activity and selectivity for the ammoxidation of alcohols to produce nitriles. Benzyl alcohol could also be directly converted to benzonitrile by MnO2 catalyst by the one-pot ammoxidation and the hydration with water which was formed by the first ammoxidation step. The deposition of gold nanoparticles (Au NPs) onto MnO2 did not enhance the ammoxidation of benzyl alcohol but promoted the hydration of benzonitrile to produce benzamide with high selectivity. In contrast, Au NPs supported on Al2O3, CuO, and CeO2 catalyzed the ammoxidation of benzyl alcohol, whereas these metal oxides themselves were inactive for the ammoxidation or showed low catalytic activity. These results have demonstrated that gold is intrinsically active as a catalyst for the ammoxidation of alcohols.
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