共价有机骨架
硝基
吸附
共价键
亚胺
吸附
傅里叶变换红外光谱
魔角纺纱
氧化物
羟胺
多孔性
酰胺
环己烷
材料科学
苯
化学工程
化学
物理化学
核磁共振波谱
有机化学
催化作用
工程类
环加成
作者
Daria Kurandina,Banruo Huang,Wentao Xu,Nikita Hanikel,Andrea Darù,Gautam D. Stroscio,Kaiyu Wang,Laura Gagliardi,F. Dean Toste,Omar M. Yaghi
标识
DOI:10.26434/chemrxiv-2023-4bq69-v2
摘要
Herein, we report the synthesis of a nitrone-linked covalent organic framework, COF-115, by combining N, N', N', N'''-(ethene-1,1,2,2-tetrayltetrakis(benzene-4,1-diyl))tetrakis(hydroxylamine) and terephthaladehyde via a polycondensation reaction. The formation of the nitrone functionality was confirmed by solid-state 13C multi cross-polarization magic angle spinning NMR spectroscopy of the 13C-isotope-labeled COF-115 and Fourier-transform infrared spectroscopy. The permanent porosity of COF-115 was evaluated through low-pressure N2, CO2, and H2 sorption experiments. Water vapor and carbon dioxide sorption analysis of COF-115 and the isoreticular imine-linked COF indicated a superior potential of N-oxide-based porous materials for atmospheric water harvesting and CO2 capture applications. Density functional theory calculations provided valuable insights into the difference between the adsorption properties of these COFs. Lastly, photoinduced rearrangement of COF-115 to the associated amide-linked material was successfully demonstrated.
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