Vertically aligned aerogel with concaved surface topography coupled ordered channel enable efficient solar-driven desalination

Solar-driven desalination has been regarded as a promising energy-saving and sustainable strategy to address the serious freshwater shortage issue. However, its performance is restricted by low solar energy utilization efficiency, water transport, and serious salt deposition. Herein, an efficient solar-driven interfacial evaporator with high solar energy utilization efficiency, fast water transport and robust salt tolerance was developed, via constructing vertically aligned sodium alginate (SA) aerogel with concave surface topography coupled ordered water transport channel structure. Concaved reflecting valley surface was assembled with 3D hierarchical photothermal networks of 2D MXene synergistic 1D carbon nanotube to enhance light absorption capacity. Concaved surface topography with multiple reflective nanostructure (angle 45°, depth 1.5 cm) owns strong sunlight concentration performance, which effectively avoid the light loss and thus enhance the light-absorption over a broad spectrum (0.3–2.5 μm). In another way, hydrophilic SA aerogel with vertically aligned structure, which also provides ordered channels for fast water/vapor transport and high salt rejection ability via strong wicking and diffusion effect. Solar-driven interfacial evaporator with such unique concaved surface topography that coupled ordered valley channels exhibits excellent evaporation rate (2.81kg m−2h−1) and remarkable solar energy utilizing efficiency (98.52 %), while with excellent antibacterial ability during continuously desalination process. Solar-driven interfacial evaporator with unique concaved surface topography coupled ordered valley channels holds great potential in sustainable water purification and desalination.