Built‐In Electric Field Boost Photocatalytic Degradation of Pollutants in Wastewater

Abstract The photocatalysis technique shows significant potential for wastewater degradation; however, the rapid recombination of photogenerated holes and electrons severely limits its photocatalytic efficiency. This situation necessitates the development of effective strategies to tackle these challenges. One well‐documented approach is built‐in electric field engineering in heterojunctions or composites, which has been shown to enhance electron transfer and thereby reduce the recombination of electrons and holes. This strategy has proven highly effective in significantly improving photocatalytic activity for the degradation of pollutants in wastewater. In this context, we summarize recent advancements in built‐in electric field engineering in photocatalysts, highlighting the fundamentals and modifications of this approach, as well as its positive impact on photocatalytic performance in the degradation of wastewater pollutants.