Dual‐Mode Hydrogels with Structural and Fluorescent Colors toward Multistage Secure Information Encryption

Constructing an anti-counterfeiting material with non-interference dual optical modes is an effective way to improve information security. However, it remains challenging to achieve multistage secure information encryption due to the limited stimulus responsiveness and color tunability of the current dual-mode materials. Herein, a dual-mode hydrogel with both independently tunable structural and fluorescent colors toward multistage information encryption, is reported. In this hydrogel system, the rigid lamellar structure of poly(dodecylglyceryl itaconate) (pDGI) formed by shear flow-induced self-assembly provides the restricted domains wherein monomers undergo polymerization to form a hydrogel network, producing structural color. The introduction of fluorescent monomer 6-acrylamidopicolinate (6APA) as a complexation site provides the possibility of fluorescent color formation. The hydrogel's angle-dependent structural color can be controlled by adjusting the crosslinking density and water content. Additionally, the fluorescence color can be modulated by adjusting the ratio of lanthanide ions. Information of dual-mode can be displayed separately in different channels and synergistically overlayed to read the ultimate message. Thus, a multistage information encryption system based on this hydrogel is devised through the programed decryption process. This strategy holds tremendous potential as a platform for encrypting and safeguarding valuable and authentic information in the field of anti-counterfeiting.