Fe-MOF with U-Shaped Channels for C2H2/CO2 and C2H2/C2H4 Separation

The development of high-performance adsorbents is critical for the low-energy separation of acetylene. Herein, we synthesized an Fe-MOF (MOF, metal-organic framework) with U-shaped channels. The adsorption isotherms of C₂H₂, C₂H₄, and CO₂ show that the adsorption capacity of acetylene is significantly larger than that of the other two gases. Meanwhile, the actual separation performance was verified by breakthrough experiments, indicating the potential to separate C₂H₂/CO₂ and C₂H₂/C₂H₄ mixtures at normal temperatures. Grand Canonical Monte Carlo (GCMC) simulation demonstrates that the framework with U-shaped channels interacts more strongly with C₂H₂ than with C₂H₄ and CO₂. The high C₂H₂ uptake and low adsorption enthalpy highlight Fe-MOF as a promising candidate for C₂H₂/CO₂ separation with a low regeneration energy.