石墨烯
材料科学
纳米复合材料
超级电容器
草酸盐
煅烧
化学工程
氧化物
纳米颗粒
降水
热液循环
纳米技术
电容
无机化学
电极
化学
冶金
催化作用
物理化学
生物化学
物理
气象学
工程类
作者
J. Barqi,S.M. Masoudpanah,M. Hasheminiasari,Ximeng Liu
标识
DOI:10.1016/j.jallcom.2022.167509
摘要
Nanoribbon-like NiCo2O4/reduced graphene oxide (RGO) nanocomposites were in situ prepared by an oxalate-assisted hydrothermal method. The various RGO contents (10, 20, and 30 wt%) were added during oxalate precipitation. The plate-like shape of oxalate precipitates was thermally decomposed into the nanoribbon-like morphology in which the NiCo2O4 nanoparticles were aligned in one direction. A network of pores between nanoparticles (∼21–14 nm) is caused by exhausting a large volume of gases during calcination at 450 °C. The specific capacity increases from 418 to 758 C g−1 at 1 A g−1 with the amounts of RGO up to 30 wt%. Furthermore, the NiCo2O4/RGO nanocomposites exhibit higher rate capability than the pristine NiCo2O4 nanoparticles. The NiCo2O4-30 wt% RGO//active carbon hybrid capacitor has a high energy density of 61 Wh kg−1 at the current density of 1 A g−1 and excellent cycling stability of 92% at 3 A g−1 after 5000 cycles.
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