电泳沉积
材料科学
电极
复合数
碳纳米管
聚偏氟乙烯
阴极
电化学
炭黑
复合材料
化学工程
电泳
纳米技术
涂层
化学
聚合物
色谱法
天然橡胶
物理化学
工程类
作者
Fatemeh Poursalehi,Mehran Javanbakht,Ahmad Ahmadi Daryakenari,Biao Gao
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2023-08-01
卷期号:170 (8): 080508-080508
标识
DOI:10.1149/1945-7111/aceb93
摘要
A binder-free composite electrode of LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811)/multi-walled carbon nanotube (MWCNT) with an extremely high NMC811 mass ratio (91 wt%) is prepared using an electrophoretic deposition process in a quick time (∼3 min). The spherical NMC811 particles are homogenously incorporated in the network created by MWCNTs, with desirable contact between these two components of the composite. The NMC811/MWCNT composite electrode showed a high first discharge capacity of 1.89 mAh cm −2 (163.4 mAh g −1 ) and 1.67 mAh cm −2 after 150 cycles at 0.1C with 88.3% capacity retention in the charge-discharge process. Compared with the conventional NMC811 electrodes prepared by the electrophoretic process (with carbon black and polyvinylidene fluoride) or doctor-blade strategy, superior electrochemical performance achieved in the binder-free composite NMC811/MWCNT electrode prepared by the electrophoretic process. This improvement is possible because the NMC811/MWCNT composite electrode could allow for a higher surface area and conductivity of the cathode material, a reactive interphase and adjustable available space in the electrode, and a homogenous distribution of the NMC particles in the MWCNT network. This scale-able, simple, binder and NMP-free, time-saving method with controllable growth deposit can be used to fabricate a variety of electrodes in storage systems.
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