Enantioselective Synthesis of Chiral Seven-Membered Ring via Rh-Catalyzed 1,4-Addition of Arylboronic Acids to Enones

A rhodium-catalyzed reaction between enones and arylboronic acids has been developed to construct chiral seven-membered ring through enantioselective 1,4-addition. This reaction offers outstanding functional group compatibility and excellent regio-, and...