阳极
电解质
材料科学
锂(药物)
快离子导体
柠檬酸
阴极
化学工程
化学
电极
工程类
物理化学
医学
有机化学
内分泌学
作者
Aamir Iqbal Waidha,Amila Salihovic,Martine Jacob,Vanita Vanita,Burak Aktekin,Kristina Brix,Kerstin Wissel,Ralf Kautenburger,Jürgen Janek,Wolfgang Ensinger,Oliver Clemens
出处
期刊:Chemsuschem
[Wiley]
日期:2023-05-26
卷期号:16 (13)
被引量:7
标识
DOI:10.1002/cssc.202202361
摘要
With the current global projection of over 130 million electric vehicles (EVs), there soon will be a need for battery waste management. Especially for all-solid-state lithium-ion batteries (lithium ASSBs), aspects of waste management and circular economy have not been addressed so far. Within such ASSBs, the use of solid-electrolytes like garnet-type Li6.5 La3 Zr1.5 Ta0.5 O12 (LLZTO) may shift focus on strategies to recover not only the transition metal elements but also elements like La/Zr/Ta. In this work, we present a two-step recycling approach using citric acid as the leaching agent to separate and recover the individual components of a model cell comprising of Li4 Ti5 O12 (LTO) anode, Li6.5 La3 Zr1.5 Ta0.5 O12 (LLZTO) garnet electrolyte and LiNi1/3 Mn1/3 Co1/3 O2 (NMC) cathode. We observe that by adjusting the concentration of citric acid, it was possible to separate the materials from each other without strong mixing of individual phases and also to maintain their principle performance characteristics. Thus, the process developed has a potential for upscaling and can guide towards considering separation capability of battery components in the development of lithium ASSBs.
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