Outside Back Cover: Splicing Them Together: Construction of Polyoxovanadate–Organic Polyhedra‐based Pyrgoscages and Catenanes (Angew. Chem. Int. Ed. 31/2025)

Inspired by the construction schemes of pyrgoscages and catenanes, advanced splicing techniques for polyoxovanadate-organic polyhedra have been developed.In their Research Article (e202504424), Peng Yang et al. integrated tetrahedral monomers into hourglass-shaped dimers via reconstruction of original vertex, introduction of exogenous vertex, and initiative of polyhedral interlock, respectively, along with the evolution of structure-dependent NH 3 adsorption behaviors.