Research and application of self-suspending proppants based on block copolymer modification in coalbed methane wells

煤层气 物理 共聚物 石油工程 甲烷 废物管理 聚合物 工程类 煤矿开采 有机化学 核磁共振 化学
作者
Qixing Zhang,Zhenbin Zhang,Bo Zhang,Tengfei Sun,Xinyang Chen,Bing Hou
出处
期刊:Physics of Fluids [American Institute of Physics]
卷期号:37 (7) 被引量:3
标识
DOI:10.1063/5.0277558
摘要

Conventional proppants exhibit limited sand-carrying capacity and incomplete gel breaking below 60 °C, resulting in inadequate fracture support and reduced stimulated reservoir volume. In this study, a self-suspending, high-salinity-resistant block copolymer was synthesized by precisely controlling the copolymer composition and topology. Based on this, a novel self-suspending proppant fracturing fluid system was developed. Its sand-carrying capacity, gel-breaking behavior, friction reduction, salt resistance, and transport performance were systematically evaluated and compared with those of emulsion polymer-based fracturing fluids. The self-suspending proppant achieved complete dispersion within 45 s and maintained suspension stability for over 25 h. It supported sand loadings up to 60%, and a small amount of proppant could carry more than ten times its weight in quartz sand. The friction reduction rate exceeded 71%, averaging 2.32% higher than that of emulsion polymer systems. The self-suspending fluid demonstrated minimal proppant settling during transport, resulting in improved placement and fracture conductivity. In contrast, emulsion polymer-based systems suffered from poor dispersion, emulsion formation, and reduced viscosity and transport distance. Field trials in the Linxing coalbed methane reservoir showed that a mixture of 10% self-suspending proppant with 26% conventional quartz sand enabled stable injection and doubled gas production compared to wells treated with emulsion polymer-based fluids. These results demonstrate the feasibility and efficiency of self-suspending proppant-based fracturing fluids for use in coalbed and shale reservoirs.
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