双金属片
催化作用
选择性
氮氧化物
反应性(心理学)
X射线光电子能谱
选择性催化还原
高分辨率透射电子显微镜
空间速度
材料科学
色散(光学)
氧气
金属
化学工程
化学
纳米技术
物理化学
透射电子显微镜
冶金
燃烧
有机化学
医学
替代医学
病理
物理
光学
工程类
作者
Kaiwen Zhao,Zhongfu Li,Tao Yan,Zhaojun Gao,Qin He,Qunfei Wang,Wenqi Liu,Jingyan Zhang,Xin Zhao,Li Liu,Conghua Liu
标识
DOI:10.1016/j.jece.2023.109757
摘要
The effect of surface synergetic oxygen vacancy constructed by bimetallic metal on CO selective catalytic reduction of NOx (CO-SCR) was investigated by loading Fe and Ni on TiO2. Herein, a series of NixFe1−x/TiO2 was prepared by the wet impregnation method. The microstructures, elemental states, and reactivity of the prepared samples were characterized by XRD, HRTEM, EPR, H2-TPD, CO-TPD, NO-TPD, and XPS. The results show that the synergistic effect between Ni and Fe effectively optimized the dispersion of Fe and constructed abundant Ni-O-Fe bonds. Furthermore, the excellent CO trapping capacity led to an increased number of cNi-□-Fe structures (SSOV), which effectively promotes NO activation at low temperatures. The in situ DRIFT spectra illustrated that N2O intermediate species rapidly transformed into N2-based species at 250 ℃, and the catalyst modified with Ni presented excellent NO conversion and N2 selectivity. The Ni0.2Fe0.8/TiO2 sample demonstrated almost 100% NO conversion, 93% N2 selectivity, and considerable stability with a gas hourly space velocity of 33,000 h-1 at 250 ℃. This work provides a novel way for the design and preparation of a bimetallic NO reduction catalyst to promote the further study of efficient CO-SCR catalysts.
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