Effects of the carbonization temperature and intermediate cooling mode on the properties of coal-based activated carbon

碳化 烧焦 活性炭 热稳定性 碳纤维 比表面积 化学工程 化学 材料科学 抗压强度 吸附 复合材料 工程类 有机化学 扫描电子显微镜 催化作用 复合数
作者
Can Zhao,Lichao Ge,Xi Li,Mingjin Zuo,Chunyao Xu,Simo Chen,Qian Li,Yang Wang,Chang Xu
出处
期刊:Energy [Elsevier BV]
卷期号:273: 127177-127177 被引量:22
标识
DOI:10.1016/j.energy.2023.127177
摘要

To optimize the production of coal-based activated carbon, the effects of carbonization temperature on the surface functional groups, crystal characteristics, degree of graphitization, thermal stability and mechanical strength of char were studied; additionally, the effects of intermediate cooling on the pore structure, adsorption capacity and mechanical strength of activated carbon were studied. The results showed that the raw material lost many functional groups during carbonization. Carbonization improved the degree of graphitization, thermal stability and mechanical strength of the raw material, and char with a high degree of graphitization, a high thermal stability and mechanical strength was obtained with a higher carbonization temperature. The activated carbon prepared by direct heating after carbonization had a more developed pore structure, adsorption capacity and mechanical strength. The pore structure of the activated carbon was mainly produced during activation. Finally, the optimal conditions were determined as follows: a carbonization temperature of 800 °C and direct heating for activation after carbonization. The yield of the activated carbon was 48.2%, the Brunauer–Emmett–Teller specific surface area was 494 m2∙g−1, the total pore volume was 0.29 cm3∙g−1, the iodine value was 785 mg∙g−1, the compressive strength was 23.5 daN, and the wear strength was 83.5%.
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