材料科学
二乙烯基苯
涂层
阳离子聚合
聚合
多边形网格
高压
微观结构
焊剂(冶金)
纳米技术
超疏水涂料
化学工程
复合材料
共聚物
高分子化学
聚合物
冶金
计算机科学
计算机图形学(图像)
工程类
工程物理
苯乙烯
作者
Chunyu Wang,Yue Shao,Kunfeng Zhang,Baichun Wu,Xianyuan Du,Xingchun Li,Xiaoyan Zhang,Fuxin Liang,Zhenzhong Yang
标识
DOI:10.1021/acsami.1c03475
摘要
When superhydrophobic meshes are used for oil/water separation, high flux and high intrusion pressure are usually compromised. Herein, a high-performance superhydrophobic stainless steel mesh membrane with a hairy-like poly(divinylbenzene) (PDVB) coating is fabricated by precipitated cationic polymerization. The synthesis is facile, which is completed in one step at ambient temperature within a short time, i.e., less than 90 s. The unique hair-like microstructure of PDVB is responsible for the superhydrophobic performance with less blockage for the pores. A higher flux for oil is achieved while keeping a high intrusion pressure. Especially, the ellipsoidal pore texture with two sharp tips can give additional high intrusion pressure. In the case of 2800 mesh, the superhydrophobic mesh displays an unprecedentedly high value of up to 22 kPa while maintaining a high flux of 2.0 × 104 L·m-2·h-1. The high intrusion pressure enables further increment of flux to 4.2 × 104 L·m-2·h-1 under a reduced pressure at a higher loading. The current high-performance superhydrophobic mesh realizes higher efficiency in separating oil/water mixtures, which is promising for practical applications, for example, in industrial extraction.
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