结晶
金属有机骨架
溶胶凝胶
纳米技术
材料科学
化学工程
化学
工程类
有机化学
吸附
作者
Jingwei Hou,Adam Sapnik,Thomas D. Bennett
出处
期刊:Chemical Science
[The Royal Society of Chemistry]
日期:2020-01-01
卷期号:11 (2): 310-323
被引量:177
摘要
The synthesis of metal-organic frameworks (MOFs) has, to date, largely been in the form of crystalline powders. However, interest in different physical morphologies of this class of materials is growing. In this perspective, we provide an overview of the structure, properties and applications of MOF monoliths. In particular, we explore the complex synthetic landscapes associated with MOF crystallization and discuss the synthetic factors leading to the formation of MOF gels, i.e. the precursor to sol-gel MOF monoliths. Finally, we provide our thoughts on the future development of this field, and attempt to highlight the importance of the MOF gel state in the discovery of new functional materials.
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