Electromagnetic (EM) wave absorption materials have drawn a lot of attention because they can effectively reduce EM wave pollution from electronic equipment. In this work, we combined ZrO 2 nanoparticles with multi-walled carbon nanotubes (MWCNTs) and explored applications of MWCNT/ZrO 2 composites in EM wave absorbing field. ZrO 2 nanoparticles with a high crystalline were synthesized by one-step hydrothermal method. Adding MWCNTs in this hydrothermal process, ZrO 2 nanoparticles aggregated together to form uneven lumps and wraps on MWCNTs surfaces. MWCNTs improved the conductivity loss and electron polarization capability of composites. The minimum reflection loss (RL) of MWCNT/ZrO 2 composites reached [Formula: see text]39.73 dB at a thickness of 2[Formula: see text]mm. Such excellent EM wave absorption properties are attributed to the dielectric loss, dipole polarizations and interfacial polarizations. This composite can be a promising candidate as high efficiency EM wave absorption material and used for commercial production because of the simple synthesis methods.