化学
氧化还原
催化作用
背景(考古学)
组合化学
杠杆(统计)
纳米技术
有机化学
计算机科学
材料科学
生物
机器学习
古生物学
作者
Terry McCallum,Xiangyu Wu,Song Lin
标识
DOI:10.1021/acs.joc.9b02465
摘要
New catalytic strategies that leverage single-electron redox events have provided chemists with useful tools for solving synthetic problems. In this context, Ti offers opportunities that are complementary to late transition metals for reaction discovery. Following foundational work on epoxide reductive functionalization, recent methodological advances have significantly expanded the repertoire of Ti radical chemistry. This Synopsis summarizes recent developments in the burgeoning area of Ti radical catalysis with a focus on innovative catalytic strategies such as radical redox-relay and dual catalysis.
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