催化作用
选择性
X射线光电子能谱
色散(光学)
粒径
钌
金属颗粒
材料科学
降水
金属
基质(水族馆)
相(物质)
化学工程
核化学
无机化学
化学
物理化学
冶金
有机化学
物理
海洋学
光学
气象学
工程类
地质学
作者
Yuxi Si,Lei Yang,Cheng-Xiang Wang,Yingliang Cheng,Siyu Yao,Lijun Wang,Xi Li
标识
DOI:10.1016/j.catcom.2022.106453
摘要
A series of supported Ru based catalysts (support = AC, Al2O3, SiO2, HZSM-5) were prepared with different methods and applied in the hydrogenation of 2,2,4,4-tetramethyl-1,3-cyclobutanedione (CBDK) to 2,2,4,4-tetramethyl-1,3-cyclobutanediol (CBDO). Detailed catalyst characterizations of XRD, TEM, BET, ICP, XPS and NH3-TPD methods were applied to investigate the support effect and influence of preparation methods. Complete conversion of the substrate was achieved with the selectivity of CBDO up to 99.1% over Ru/AC catalysts. The superiority of Ru/AC catalyst prepared with chemical precipitation method over other counterparts were attributed to the larger specific surface area, smaller metal particle size and better Ru dispersion, which was more favorable for the hydrogenation of CBDK.
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