In the title compound, C10H11N3O5S, the 2,4-dinitrophenyl fragment is connected by an S atom to the morpholine ring, which is in a chair conformation. The ortho- and para-nitro groups are slightly twisted out of the plane of the benzene ring. The molecules are linked into C(7) and C(10) chains by two intermolecular C—H⋯O hydrogen bonds.