介孔材料
催化作用
沸石
二甲醚
甲醇
吸附
ZSM-5型
浸出(土壤学)
化学工程
选择性
焦炭
化学
无机化学
材料科学
吸附
有机化学
土壤水分
土壤科学
工程类
环境科学
作者
Małgorzata Rutkowska,Daniel Macina,N. Mirocha-Kubień,Zofia Piwowarska,Lucjan Chmielarz
标识
DOI:10.1016/j.apcatb.2015.03.006
摘要
A new type of micro–mesoporous materials with properties of ZSM-5 zeolite was tested as catalysts for the synthesis of dimethyl ether (DME) from methanol. The catalytic performance of ZSM-5 was improved by generation of mesoporosity using desilication method (alkaline leaching of framework Si). It was shown that controlled modification of the porous structure and acidity of the zeolitic samples strongly influences their catalytic activity, selectivity and stability in the process of DME synthesis. Desilication of ZSM-5 zeolite resulted in a development of the mesoporous structure and enhancement of its acidity, what was confirmed by N2-sorption measurements, IR-DRIFT spectroscopy and NH3-TPD. Desilicated zeolite samples exhibited higher catalytic activity and stability in the process of DME synthesis in comparison to parent ZSM-5. Moreover, micro–mesoporous zeolites were more resistant for poisoning by coke deposits in comparison to conventional ZSM-5 catalyst.
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