ChemInform Abstract: Synthesis of 1H‐Indole‐3‐carboxamidines Through a Palladium‐Catalyzed Three‐Component Reaction Involving Isocyanide Insertion as a Key Step.

Abstract A new type of indoles having a carboxamidine substituent at the 3‐position are efficiently synthesized through a novel Pd‐catalyzed three‐component reaction of o‐alkynyltrifluoroacetanilines, isocyanides, and amines.