Conjugated Cobalt Polyphthalocyanine as the Elastic and Reprocessable Catalyst for Flexible Li–CO2 Batteries

Abstract Li–CO 2 batteries represent an attractive solution for electrochemical energy storage by utilizing atmospheric CO 2 as the energy carrier. However, their practical viability critically depends on the development of efficient and low‐cost cathode catalysts for the reversible formation and decomposition of Li 2 CO 3 . Here, the great potential of a structurally engineered polymer is demonstrated as the cathode catalyst for rechargeable Li–CO 2 batteries. Conjugated cobalt polyphthalocyanine is prepared via a facile microwave heating method. Due to the crosslinked network, it is intrinsically elastic and has improved chemical, physical, and mechanical stability. Electrochemical measurements show that cobalt polyphthalocyanine facilitates the reversible formation and decomposition of Li 2 CO 3 , and therefore enables high‐performance Li–CO 2 batteries with large areal capacity and impressive cycling performance. In addition, the elastic and reprocessable property of the polymeric catalyst renders it possible to fabricate flexible batteries.