A catalytic asymmetric one-pot [3+2] cyclization/semipinacol rearrangement sequence: an efficient construction of a multi-substituted 3H-spiro[benzofuran-2,1′-cyclopentane] skeleton

We report an asymmetric construction of multi-substituted 3H-spiro[benzofuran-2,1’-cyclopentane]s with three new stereocenters and two new ring systems.