超级电容器
材料科学
溶剂
多孔性
化学工程
电容
电化学
Crystal(编程语言)
金属有机骨架
储能
电极
纳米技术
化学物理
物理化学
化学
复合材料
有机化学
热力学
吸附
物理
工程类
功率(物理)
程序设计语言
计算机科学
作者
Changli Wang,Xinran Li,Wei Yang,Yuxia Xu,Huan Pang
标识
DOI:10.1016/j.cclet.2021.04.017
摘要
Metal-organic frameworks (MOFs) with porous crystal structures have attracted extensive attention in application of energy storage and conversion, owing to their regularity, porosity, large specific surface area, etc. In this work, Co-MOF-74 microflower has been successfully prepared via a controllable solvent regulation strategy. Through modulating the polarity of the solvent, crystals grow in certain preferred orientation and Co-MOF-74 with various morphologies were obtained. Thereinto, the energy storage performance of Co-MOF-74 microflower was measured in both three-electrode system and asymmetric supercapacitor device (specific capacitance of 164.2 F/g at 0.5 A/g in the three-electrode system and 62.5 F/g at 1 A/g in the asymmetric supercapacitor device). This can be attributed to the preferred crystal orientation resulting in a regular and uniform microflower, which is of great significance to electronic interfacial exchange and ion transfer during electrochemical reactions.
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