化学
小学(天文学)
溶剂
催化作用
芳基
有机化学
组合化学
金属
光化学
硝基
环加成
天文
物理
烷基
作者
Álisson Silva Granato,Giovanni W. Amarante,Javier Adrio
标识
DOI:10.1021/acs.joc.1c01888
摘要
An environmentally benign protocol for the generation of nitrones from benzylic secondary amines via catalyst-free oxidation of secondary amines using H2O2 in MeOH or CH3CN is described. This methodology provides a selective access to a variety of C-aryl nitrones in yields of 60 to 93%. Several studies have been performed to shed light on the reaction mechanism and the role of the solvent.
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