脱氢
催化作用
惰性气体
氢
化学
冷凝
无机化学
还原气氛
吸附
过渡金属
氧化物
大气(单位)
混合氧化物
有机化学
热力学
物理
作者
Jorge Quesada,Laura Faba,Eva Dı́az,Salvador Ordóñez
标识
DOI:10.1016/j.apcata.2018.04.022
摘要
The effect of the presence of reduced Co and Ni (chosen as representative metals because of their good activity for dehydrogenation reactions) on the catalytic performance of basic mixed oxide (Mg-Al) for ethanol condensation is studied in this work. This effect has been studied both in absence and in presence of hydrogen, and considering the different steps of this complex reaction. Globally, best results were obtained with Co/MgAl, under reducing atmosphere, at mild temperature (below 600 K). At these conditons, 1-butanol production rates are up to eight times higher than the obtained with Mg-Al under inert atmosphere. Co has a marked activity in the dehydrogenation step, that prevails over its less relevant activity in aldolization and hydrogenation reactions. This result indicates the relevant role of this first reaction step. DRIFT spectroscopy analyses were carried out to support the experimental results and to identify the role of hydrogen and metals on the oligomerization and permanent adsorption processes, which can produce the deactivation of the catalyst.
科研通智能强力驱动
Strongly Powered by AbleSci AI