变质作用
地质学
变质岩
矿物学
结壳
流体力学
分层
流体包裹体
地球化学
均质化(气候)
碳酸盐
多孔性
岩石学
热力学
岩土工程
化学
热液循环
生物多样性
地震学
物理
有机化学
生物
植物
生态学
摘要
Research over the last four decades on carbonate rocks of the Waterville limestone, Maine, U.S.A., has contributed to the development of both concepts and methodologies for understanding fuid-rock interaction during regional metamorphism, including: (1) buffering of fluid composition by mineral reactions, (2) infiltration of carbonate rocks by aqueous fluids, (3) petrologic fluid-rock ratios, (4) infiltration-driven metamorphism, (5) one- and two-dimensional continuum models for coupled fluid flow and mineral reaction, (6) time-integrated fluid fluxes, and (7) channelized, horizontal fluid flow in the direction of increasing temperature within chemically isolated layers. Disagreement between the last concept and both hydrodynamic models for metamorphic fluid flow and empirical evidence for homogenization of fluid composition at a scale much larger than layer thickness motivated development of the latest models for coupled fluid flow and mineral reaction in the Waterville limestone. The new models consider a flow medium composed of layers that differ in the initial amounts and compositions of minerals, both horizontal flow in the direction of increasing temperature and vertical flow in the direction of decreasing pressure and temperature, significant but imperfect homogenization of fluid composition across layering by CO2-H2O interdiffusion, and infiltration by fluids that are spatially variable in composition on the kilometer scale with CO2 content increasing with increasing grade of metamorphism. The new models reproduce measured progress of the biotite-forming reaction in the Waterville limestone over a range of spatial scales spanning six orders of magnitude, from differences in reaction progress of up to a factor of ~100 between adjacent centimeter-thick layers to the coexistence of mineral reactants and products over a distance of ~13 km parallel to the metamorphic field gradient. Results imply that the present spatial distributions of reaction progress represent a steady state achieved when rocks closely approached equilibrium with the infiltrating fluid during metamorphism. The new models resolve what for many years appeared to be fundamental discrepancies among petrologic data for regionally metamorphosed carbonate rocks, hydrodynamic models of regional metamorphism, and the length scales of mass transport of volatiles across layering by diffusion.
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