After the principle of exploding wires was studied,the experiments to prepare coatings of ultrafine crystaline WCCo horniness alloys have been carried out with an authors made exploding wires device in vacuum or ambient environment.The maximum micro hardness of the WCCo coatings is up to Hv=2190,i.e. 1.4 times of the samples without coatings.A transition layer between the coating and the substrate surface has been found,which has a microstructure different from both of the coating and the substrate.The micro hardness,microstructure,its composition and bound strength of the coatings are analyzed in detail.