Pore-Scale Investigation of Micron-Size Polyacrylamide Elastic Microspheres (MPEMs) Transport and Retention in Saturated Porous Media

多孔介质 聚丙烯酰胺 微球 多孔性 材料科学 比例(比率) 化学工程 复合材料 高分子化学 工程类 物理 量子力学
作者
Chuanjin Yao,Guanglun Lei,L. M. Cathles,Tammo S. Steenhuis
出处
期刊:Environmental Science & Technology [American Chemical Society]
卷期号:48 (9): 5329-5335 被引量:99
标识
DOI:10.1021/es500077s
摘要

Knowledge of micrometer-size polyacrylamide elastic microsphere (MPEM) transport and retention mechanisms in porous media is essential for the application of MPEMs as a smart sweep improvement and profile modification agent in improving oil recovery. A transparent micromodel packed with translucent quartz sand was constructed and used to investigate the pore-scale transport, surface deposition-release, and plugging deposition-remigration mechanisms of MPEMs in porous media. The results indicate that the combination of colloidal and hydrodynamic forces controls the deposition and release of MPEMs on pore-surfaces; the reduction of fluid salinity and the increase of Darcy velocity are beneficial to the MPEM release from pore-surfaces; the hydrodynamic forces also influence the remigration of MPEMs in pore-throats. MPEMs can plug pore-throats through the mechanisms of capture-plugging, superposition-plugging, and bridge-plugging, which produces resistance to water flow; the interception with MPEM particulate filters occurring in the interior of porous media can enhance the plugging effect of MPEMs; while the interception with MPEM particulate filters occurring at the surface of low-permeability layer can prevent the low-permeability layer from being damaged by MPEMs. MPEMs can remigrate in pore-throats depending on their elasticity through four steps of capture-plugging, elastic deformation, steady migration, and deformation recovery.
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