Characterization of ZTA Composite Ceramic/Ti6Al4V Alloy Joints Brazed by AgCu Filler Alloy Reinforced with One-Dimensional Al18B4O33 Single Crystal

Al18B4O33 whiskers were used as a reinforcer to study the effect of one-dimensional single crystal on the quality improvement of ZTA composite ceramic/Ti6Al4V alloy joints brazed by AgCu alloy. The microstructure of the joint with whisker additions was characterized in detail. The effects of brazing temperature on the microstructure and shear strength of the brazed joints were investigated. The results showed that the whiskers reacted with the liquid alloy during the brazing process and continuous (Cu,Al)3Ti3O layers were formed in contact with the residual whiskers. The addition of 2 wt.% Al18B4O33 whiskers into AgCu filler alloy can delay the growth of the (Cu,Al)3Ti3O layer on the ZTA side, and can significantly restrain the growth of the Ti-Cu compound region over a brazing temperature range of 800~875 °C. Because of the one-dimensional reinforcement, the temperature window for obtaining ZTA/Ti6Al4V joints with shear strength values higher than 50 MPa was extended, and the maximum shear strength of the joints reached 56 MPa.