Synergistic modification of polylactic acid by oxidized straw fibers and degradable elastomers: A green composite with good strength and toughness

Polylactic acid-based (PLA) composites are widely used in biomedicine, electrical components, food packaging and other fields, but their unsatisfactory mechanical properties such as high brittleness and poor toughness, cause problems in functional applications. This work developed a green and environmentally friendly strategy to improve PLA mechanical properties. Flexible polybutylene succinate (PBS) and alkaline hydrogen peroxide (AHP) treated straw fibers (SF) synergistically modified PLA. AHP is decomposed into a large amount of HOO-, which oxidizes the hydroxyl groups in SF to carboxyl groups to obtain oxidized straw fiber (OSF), which reacts with PLA in the molten state to form new ester bonds. The tensile strength of the OSF/PLA composite is 41.78 MPa, 38 % higher than the SF/PLA composite. The impact toughness of OSF/PBS/PLA composite is 14.47 KJ/m 2 increased by 54 % after the adding PBS, while the tensile strength was also better than the control group. The synergistic action of PLA and PBS in OSF is attributed to the formation of new chemical bonds, efficient crystallization, and compatible interface. This study provides a new strategy to produce fiber-reinforced PLA composites with good toughness. It takes positive significance for developing degradable plastics with good performance and controllable cost. • Oxidized straw fiber successfully strengthens modified polylactic acid. • A green composite with good impact resistance and tensile properties is prepared. • The synergistic modification mechanism of OSF and PBS on PLA is explored.